Hi,
You can not set the ValidatorCalloutExtender's backcolor, because it has no this attribute.
You can try to download the ajax control toolkit's source file of the ValidatorCalloutExtender, you will find the background of the validatorCalloutExtender control has been set in the js file, for example:
//
// iconCell
//
iconCell.width = 20;
iconCell.style.borderTop = "1px solid black";
iconCell.style.borderLeft = "1px solid black";
iconCell.style.borderBottom = "1px solid black";
iconCell.style.padding = "5px";
iconCell.style.backgroundColor = 'LemonChiffon';
so if you want to set it, you can try to get it from the ValidatorCalloutBehavior.js file, and set it by javascript method.
Therefore, it is not easy to set this control's background.
Please remember to mark the replies as answers if they help and unmark them if they provide no help.
Yours sincerely,
Amanda Wang
Microsoft Online Community Support